seems like smite still doesnt apply ailments except for those that youve picked on the skill tree.
I used the conversion to lightning node to get a lightning tag, then equipped unique boots fro 150% shock chance. tested on mobs and dummy neither procs neither direct casts of smite DO NOT apply shock. I havent tested with ignite but i suspect same thing happening.
I also have a question does this conversion node supposed to converse all shock chance(from items too) or only from skill tree?